Methylammonium chloride

Methylammonium chloride in an organic halide with a formula of CH3NH3Cl. It is an ammonium salt composed of methylamine and hydrogen chloride. The primary application for the methylammonium halides is as a component of perovskite (structure) crystalline solar cells.[3] Methylammonium iodide is the most commonly used, whereas using the chloride instead of, or as minor substituent to, the iodide provides the ability to tune the absorption, conductivity, and apparent bandgap.[4]

Methylammonium chloride
The methylammonium cation
The chloride anion
Names
IUPAC name
Methylazanium chloride
Systematic IUPAC name
Methanaminium chloride
Other names
  • Methylamine hydrochloride
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
ECHA InfoCard 100.008.906
EC Number
  • 209-795-0
  • InChI=1S/CH5N.ClH/c1-2;/h2H2,1H3;1H
    Key: NQMRYBIKMRVZLB-UHFFFAOYSA-N
  • C[NH3+].[Cl-]
Properties
CH3NH3Cl
Molar mass 67.51804 g/mol
Appearance White crystals [1]
Hazards[2]
Main hazards irritant
GHS labelling:
Warning
H302, H315, H319, H335
P261, P305+P351+P338
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

References

  1. "Methylammonium chloride". Greatcell Solar Materials. Retrieved 10 April 2021.
  2. "GESTIS-Stoffdatenbank". gestis.dguv.de. Retrieved 11 March 2021.
  3. Li, Hangqian. (2016). "A modified sequential deposition method for fabrication of perovskite solar cells". Solar Energy. 126: 243–251. Bibcode:2016SoEn..126..243L. doi:10.1016/j.solener.2015.12.045.
  4. Zhao, X. (2021). "Methylammonium Chloride reduces the bandgap width and trap densities for efficient perovskite photodetectors". Journal of Materials Science. 56: 9242–9253. doi:10.1007/s10853-021-05840-2.
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