Table of spherical harmonics

This is a table of orthonormalized spherical harmonics that employ the Condon-Shortley phase up to degree . Some of these formulas give the "Cartesian" version. This assumes x, y, z, and r are related to and through the usual spherical-to-Cartesian coordinate transformation:

Complex Spherical harmonics

For = 0, …, 5, see.[1]

= 0

= 1

= 2

= 3

= 4

= 5

= 6

= 7

= 8

= 9

= 10

Visualization of Complex Spherical Harmonics

2D polar/azimuthal angle maps

Below the complex spherical harmonics are represented on 2D plots with the azimuthal angle, , on the horizontal axis and the polar angle, , on the vertical axis. The saturation of the color at any point represents the magnitude of the spherical harmonic and the hue represents the phase.

Visual Array of Complex Spherical Harmonics Represented as 2D Theta/Phi Maps

Polar Plots

Below the complex spherical harmonics are represented on polar plots. The magnitude of the spherical harmonic at particular polar and azimuthal angles is represented by the saturation of the color at that point and the phase is represented by the hue at that point.

Visual Array of Complex Spherical Harmonics Represented with Polar Plot

Polar Plots with Magnitude as Radius

Below the complex spherical harmonics are represented on polar plots. The magnitude of the spherical harmonic at particular polar and azimuthal angles is represented by the radius of the plot at that point and the phase is represented by the hue at that point.

Visual Array of Complex Spherical Harmonics Represented with Polar Plot with Magnitude Mapped to Radius

Real spherical harmonics

For each real spherical harmonic, the corresponding atomic orbital symbol (s, p, d, f, g) is reported as well.

For = 0, …, 3, see.[2][3]

= 0

= 1

= 2

= 3

= 4

Visualization of Real Spherical Harmonics

2D polar/azimuthal angle maps

Below the real spherical harmonics are represented on 2D plots with the azimuthal angle, , on the horizontal axis and the polar angle, , on the vertical axis. The saturation of the color at any point represents the magnitude of the spherical harmonic and the hue represents the phase.

Visual Array of Real Spherical Harmonics Represented as 2D Theta/Phi Maps

Polar Plots

Below the real spherical harmonics are represented on polar plots. The magnitude of the spherical harmonic at particular polar and azimuthal angles is represented by the saturation of the color at that point and the phase is represented by the hue at that point.

Visual Array of Real Spherical Harmonics Represented with Polar Plot

Polar Plots with Magnitude as Radius

Below the real spherical harmonics are represented on polar plots. The magnitude of the spherical harmonic at particular polar and azimuthal angles is represented by the radius of the plot at that point and the phase is represented by the hue at that point.

Visual Array of Real Spherical Harmonics Represented with Polar Plot with Magnitude Mapped to Radius

See also

References

Cited references

  1. D. A. Varshalovich; A. N. Moskalev; V. K. Khersonskii (1988). Quantum theory of angular momentum : irreducible tensors, spherical harmonics, vector coupling coefficients, 3nj symbols (1. repr. ed.). Singapore: World Scientific Pub. pp. 155–156. ISBN 9971-50-107-4.
  2. C.D.H. Chisholm (1976). Group theoretical techniques in quantum chemistry. New York: Academic Press. ISBN 0-12-172950-8.
  3. Blanco, Miguel A.; Flórez, M.; Bermejo, M. (1 December 1997). "Evaluation of the rotation matrices in the basis of real spherical harmonics". Journal of Molecular Structure: THEOCHEM. 419 (1–3): 19–27. doi:10.1016/S0166-1280(97)00185-1.

General references

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