Chromium(II) iodide

Chromium(II) iodide is the inorganic compound with the formula CrI2. It is a black solid. The compound is made by thermal decomposition of chromium(III) iodide. It adopts the cadmium iodide structure, with ribbon-like strands formed of interconnected square planar CrI4 units which share iodide ligands.[1][2]

Chromium(II) iodide
Names
Other names
chromous iodide
Identifiers
  • 13478-28-9
3D model (JSmol)
ChemSpider
  • InChI=1S/Cr.2HI/h;2*1H/q+2;;/p-2
    Key: BMSDTRMGXCBBBH-UHFFFAOYSA-L
  • [Cr+2].[I-].[I-]
Properties
CrI2
Molar mass 305.8050 g·mol−1
Appearance black deliquescent solid
Density 5.196 g/cm3
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

References

  1. Tracy, J. W.; Gregory, N. W.; Stewart, J. M.; Lingafelter, E. C. (1962). "The crystal structure of chromium(II) iodide". Acta Crystallographica. 15 (5): 460–463. doi:10.1107/S0365110X62001152.
  2. Vest, Brian; Hermann, Andreas; Boyd, Peter D. W.; Schwerdtfeger, Peter (2010). "Nucleation of Antiferromagnetically Coupled Chromium Dihalides: From Small Clusters to the Solid State". Inorganic Chemistry. 49 (7): 3169–3182. doi:10.1021/ic901949a.
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